Gasification

Carbon Conversion

The intensive mixing in a fluid bed has its advantages in promoting excellent mass and heat transfer. In fact, a fluid bed approaches the ideal of a continuously stirred tank reactor. This does, however, have its disadvantages. There is wide range of residence times for the individual particles, which are distributed evenly over the whole volume of the bed. Thus removal of fully reacted particles, which consist only of ash, will inevitably be associated with removal of unreacted carbon. The best of existing fluid-bed processes only have a carbon conversion of 97%. This is in contrast to moving-bed and entrained-flow processes, where carbon conversions of 99% can be obtained. Only in pressurized biomass gasification have fluid-bed proc­esses efficiencies of 99% been reported (Kersten 2002).

Many attempts (e. g., Synthane or Ну-Gas) have been and are being made to intro­duce some staging effect by which the last carbon in the ash to be discharged is converted with (part of) the incoming blast, but this remains difficult as fluid beds lend themselves poorly to staging because of the “no-go” temperature zones men­tioned earlier in this chapter.

Ash

The ash of fluid-bed gasifiers comes available in a highly leachable form. This problem is exacerbated when limestone is added in order to bind the sulfur present in the gas and to avoid the need for wet sulfur removal processes. The limestone is never completely converted into gypsum, and hence the ash will always contain unconverted lime. Similar problems are associated with fluid-bed combustion processes. Adding limestone to the fluid bed is an example of doing two things at once. It looks elegant, but you are never free to optimize both desulfurization and gasification or combustion.

Ash particles are removed from below the bed and/or from the cyclones in the top of the bed. In the former case they are sometimes used for preheating the blast. Fluid-bed gasifiers may differ in the manner in which ash is discharged (dry or agglomerated) and in design aspects that improve the carbon conversion. Some “carbon stripping” of the char containing ash to be discharged with incoming oxygen is possible.

Gasification

Liquid Wastes

Organic Chemical Waste. Organic wastes from chemical production vary as widely as the processes from which they originate. One published example is the feedstock to a waste gasification plant at …

Carbon Management

In the Texaco process, soot is extracted from the carbon-water mixture with naphtha and recycled with the feedstock to the reactor where it is gasified to extinction. The black water …

Common Issues

Operating Temperature Any fluid bed depends on having the solid particles of a size that can be lifted by the upward flowing gas. A large portion (over 95%) of the …

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